co2 extraction vs cold-pressed, who is better?

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CO2 extraction vs cold pressed

Okay, so if cold pressed CBD is so great why do most companies use co2 extraction? Whilst cold pressed hemp produces a higher quality CBD oil, it also results in a lower yield.

There is no doubt that CO2 is the best when it comes to extracting essential oils with high economic added value.

Supercritical CO2 extraction ensures the freshness of flavour, colour & odor – as well as quality, especially when used to create oils which are highly susceptible to oxidation & rancidity. While other extraction methods are competitively comparable, they cannot all be rated equally. And how oils are manufactured is essential to how the product will hold up – both on the shelf and on the market. 

Because oxygen-free environments and low temperatures are particularly important, especially for fragile ingredients such as Cannabis or Sea Buckthorn Seeds.

Why lack of oxygen can make sense

In contrast to cold pressing, with CO2 extraction no oxygen comes into contact with the plant material to be processed. In this way, the sensitive natural substances remain protected from oxidation, are more durable and cannot become rancid so quickly.

The CO2-extracted oils are considered more fragrant and richer.

By keeping temperatures low and extracting all the ‘active’ components, we’re able to preserve and protect the complete botanical, active substances, and terpenes of the CBD.

Another example, a direct comparison has shown that the proportion of phytosterols in CO2 extraction is higher than in cold pressing.

It is precisely the phytosterols obtained from oil-containing plants that balance the skin\’s moisture balance and are therefore often used for dry skin. They have an anti-itch and anti-inflammatory effect.

Low temperature extraction

Whilst some heat is generated from mechanical friction, this is significantly lower than other methods including popular CO2 extraction. Many delicate plant phytonutrients are temperature sensitive and are often degraded or depleted using higher temperature extraction methods. Keeping temperatures low results in the extracted oil being far richer in these sensitive nutrients, contributing to the entourage effect and producing greater efficacy of the end product.

Cold pressed hemp oil is also considered to have a better flavour and aroma, which is down to the higher concentration of terpenes and monoterpenes found within the extract.

Whilst cold pressed hemp produces a higher quality CBD oil, it also results in a lower yield. Higher temperatures reduce overall nutrient content but the heat makes the plant matter softer and easier to breakdown, resulting in higher yields and ultimately higher profits.

CO2 extraction also leaves absolutely no solvent residues, so the final oil is impeccably pure. This includes the incredible natural color and smell. You only have to see how orange, concentrated and herbaceously-scented Sea Buckthorn Seeds bio regenerate is to witness CO2 extracts at their best.

Last but by no means least, the low temperature and lack of waste streams/emissions make it an extremely environmentally-friendly process.

The primary benefits of supercritical CO2 extraction
  • Limited rancidity – no pre-exposure to oxygen means reduced chances of spoilage, so the product and its benefits keep for as long as possible
  • Stability – fragile oils are a higher quality when extracted with low or no heat
  • Selective process control – obtaining constituents that hold the best healing properties, adding to its effectiveness
  • Environmentally sound – using carbon dioxide (a natural byproduct of human existence) for pharmacological & medical practices is a completely natural and safe method for oil extraction

The advantages of co2 method of extraction to conventional cold-pressing

Lower temperature of operation: heat-sensitive components remain intact;
Exclusion of oxygen: oxidation-sensitive components remain intact;
Higher selectivity and higher mass transfer which leads to a higher yield and a longer shelf-life;
Cleaner process both in terms of environmental impact and the yield;
Longer shelf-life of the product compared to conventional extraction methods; and a
Finer flavour and scent compared to conventional products.

There are some minor disadvantages to SCF extraction

Higher costs and technological requirements compared to a conventional extraction of maceration;
Usually a very intense colour of the extract; and
CO2 extracts generally cost more.

Example comparison: co2 extraction vs cold pressed

We provide the extraction table of essential oils extracted by two extraction methods and the extraction experiment of walnut oil for comparison:

To compare the oxidative stability of cold-pressed and supercritical CO2-extracted walnut oil under dark and light conditions, we measured the peroxide value of walnut oil and conducted the sensory evaluation.

Cold pressing

Cold pressing is a traditional process for oil production. Because this method is relatively inefficient, labor-intensive, and low in oil yield, cold pressing is rarely used for the oil production of bulk oils. However, because this method is a physical method, it is pressurized without heating up and does not affect oil and vegetable protein, so it is suitable for the preparation of special oil such as walnut oil.

CO2 extraction

The supercritical CO2 extraction process is currently recognized as one of the most ideal separation technologies. It is an advanced technology that utilizes CO2 in a supercritical state under high pressure to extract and separate various useful substances. Because CO2 is non-toxic, non-polluting, and the separation of CO2 and oil is relatively simple, and the operating temperature is relatively low, it is also suitable for the preparation of walnut oil.

Materials and Equipment

Walnut kernels: from Changzhi, Shanxi, fresh and dried;
Supercritical CO2 extraction machine: L-02 (1 lb co2 extractor);
Fast hydraulic oil press, type 6YY-190;
Constant temperature incubator: HPX-9082;
Light meter: TES-1332 type.
Main reagents: chloroform, acetic acid, potassium iodide, sodium thiosulfate, 0.5% starch solution.

Supercritical CO2 Extraction Process

Supercritical CO2 extraction of walnut oil: pulverize the walnut kernels to about 30 mesh, put it into the extraction kettle, adjust the extraction kettle pressure to 32MPa, the extraction temperature to 40℃, and extract for 3.5h; the pressure of the separation kettle I am 12MPa, the temperature is 40℃; the separation The pressure of the kettle II is 6.5MPa, the temperature is 40℃; the flow rate of CO2 is 10kg/h. Collect 400 ml of extracted oil.

Cold-pressed walnut oil

Cold pressing to make walnut oil: wrap the walnut kernels with cloth and put them into the barrel, adjust the pressure to 60MPa for cold pressing, the walnut oil slowly flows out, collect 400 ml, and centrifuge the walnut oil for 10 minutes at a speed of 6000 r/min, Remove impurities.

Comparative experiment of CO2 extraction and cold pressing of walnut oil

Referring to the Schaal oven method, create the conditions for the accelerated test: in a dark incubator, adjust the temperature to 60°C and the relative humidity to 70%;
In a lighted incubator, adjust the temperature to 40°C, the relative humidity to 70%, and the illumination to 500lx. Measure 6 parts of 50ml cold-pressed walnut oil into 100ml conical flasks with stoppers, tighten the caps, put three of them in a dark incubator, and the other three in a light incubator In the same way, measure 6 parts of 50ml supercritical CO2 extracted walnut oil and put them into 100ml conical flasks with stopper respectively, put three of them into a dark incubator, and the other three into a light incubator middle. The samples were placed in an incubator for 20 d, the peroxide value was measured every 5 d, and the average value of the peroxide value of three identical samples in the same incubator was calculated.

Determination of Peroxidation Value of Walnut Oil

According to the method specified in GB/T5009.37-1996, the peroxide value (PV) of cold-pressed walnut oil and supercritical CO2 extracted walnut oil under dark and light conditions was determined.

  • Under the conditions of a temperature of 60℃, relative humidity of 70%, and darkness, the peroxide value of walnut oil extracted by supercritical CO2 is higher than that of cold-pressed walnut oil, which indicates that the oxidation stability of walnut oil extracted by supercritical CO2 is higher than that of cold-pressed walnut oil. low oil.
  • Under the conditions of a temperature of 40℃, relative humidity of 70% and the illumination of 500lx, the peroxide value of walnut oil prepared by cold pressing is higher than that of walnut oil extracted by supercritical CO2, which shows that the stability ratio of cold-pressed walnut oil under this condition is higher than that of walnut oil extracted by supercritical CO2. The stability of walnut oil extracted by supercritical CO2 is low.
co2 extractor
1000l co2 extractor

CO2 extraction vs cold pressed

The purpose of the two storage conditions in the test is different: the temperature of 60°C, the relative humidity of 70%, and the absence of light are to measure the properties of walnut oil auto-oxidation; the temperature of 40°C, the relative humidity of 70%, and the light intensity of 500lx. It is to measure the properties of walnut oil photo-oxidation. This is of great significance for guiding the packaging method of walnut oil: cold-pressed oil has poor photo-oxidative stability, so it is best to use dark packaging materials to reduce the influence of light; walnut oil extracted by supercritical CO2 fluid is relatively stable due to photo-oxidation. Strong, can be packaged with transparent material.

Dark conditions

The stability of the walnut oil extracted by supercritical CO2 was poor in the absence of light, which may be due to the relatively low VE content in it. VE is a natural antioxidant. Although the temperature in the supercritical CO2 fluid extraction process is only a dozen degrees Celsius higher than that in the cold pressing process, the duration is longer, dozens of times that of the cold pressing process, which may affect the anti-oxidant properties of VE. Oxidation effect.

Light conditions

Under light conditions, the presence of chlorophyll reduces the photo-oxidative stability of the oil. Cold-pressed oils are less stable, possibly because of their higher chlorophyll content. Chlorophyll is easily decomposed when the temperature increases and lasts for a long time. The higher temperature in the supercritical CO2 extraction process makes part of the chlorophyll decompose, and the chlorophyll content is very small, so its photo-oxidative stability is strong.

The peroxide value mainly measures the content of hydroperoxide, and hydroperoxide is easy to decompose, so the peroxide value is often used to measure the initial oxidation degree of oil, and cannot fully reflect the oil with a deeper degree of oxidation. However, hydroperoxides have an unpleasant taste after decomposing into small molecules such as aldehydes, ketones, acids, etc., which can be measured by sensory evaluation. In this way, the oxidation stability of walnut oil can be truly reflected through the determination of peroxide value and sensory evaluation.

Evening primrose pressed oilEvening primrose CO2 extract
INCI nameOenothera biennis oilOenothera biennis seed extract
Major Components
Density (20 oC) g/cm30.9250.910-0.940
Refractive index (20 oC)1.47591.4760-1.4810
Sap. Value mg KOH/g193193
Fatty acid composition
Palmitic acid (C16:0)6.3%6.1%
Stearic acid (C18:0)2.2%1.9%
Oleic acid (C18:1)7.2%7.1%
Linoleic acid (C18:2)73.3%74.5%
Gamma Linolenic acid (C18:3)8.9%9.7%
Palmitoleic acid (C16:1)TraceTrace
Vaccenic acid (C18:1)TraceTrace
Alpha-linolenic acid (C18:3)TraceTrace
Arachidic acidTraceTrace
Tocopherols770 ppm300 ppm
Cardamon EOCardamon CO2 extract
INCI nameElettaria cardamomum seed oilElettaria cardamomum fruit extract
Major components
Terpinyl acetate40.44%50.0%
1,8-cineole (Eucalyptol)29.90%25.40%
Linalyl acetate5.02%6.30%
Alpha terpineol1.79%2.20%
Alpha pinene1.61%0.68%

Further reading

cold press working
cold press working

What is cold press?

The cold press method is a type of mechanical extraction that extracts oil from oilseeds, peels, or fruit of the plant. It is also known as mechanical separation or expression or expeller pressing. The technique is specifically used for citrus family oils like orange, lemon as the essential oils are stored in the skin or epicarp of citrus fruits.

The process is termed as ‘cold’ press because there is no heat involved. Naturally oil seeds can be just crushed to extract oil. Sesame seeds, coconut, groundnut are some raw materials from which oil can be retrieved by just pressing.

History of cold-press method

The origin of cold-pressed oil dates back to the Indus Valley Civilization. Burnt sesame seeds and an oil pressing machine was found in the remains of Harappa which were dated 5000 years old.
The cold-press method of extraction received its name from the German words kalt geschlagen. The word mentioned means ‘cold pummeling’. It is believed that it refers to the intensive pressure that seeds and fruits bear.
The process was pioneered in Italy in the 19th century and it then expanded to Brazil, California, and Florida.
Chekku, Ghani, and Kholu are some spoken words that are commonly used in India to depict cold press oils. These words refer to the oil pressing machine which is used to extract oil.

Cold press process of Extraction

Cold press method is a mechanical separation process where crushing of nuts or seeds takes place and forcing out of oil through pressure is done.

In ancient days, a long cylindrical contraption known as ‘Ghani’ was used for the extraction of oil from oilseeds. It was mentioned in some books that Ghani was a pestle and mortar device that was made of stone or wood. It involves the extraction of oil under pressure from oil-bearing seeds. This is regarded as the uncomplicated method of oil extraction. It also did not involve too much generation of heat. Nowadays these ghanis are replaced by modern extraction machines.

Mechanical press methods are also referred to as solid-liquid phase separation used for oil extraction with oil content below 20%. Pressure is an important parameter that is applied for extraction.

Temperature is applied optionally, a process without temperature refers as cold press method and that with temperature application called as hot press method.

In earlier days, cold pressed oils were extracted by hand and made use of specialized sponges that helped to absorb plants oil and liquid. These sponges were then pressed in a vice-like device over a container. This helped to separate oil from rest of the plant liquid. But the process was labor intensive and also time-taking. In present scenario, the process is less labor intensive. Even modern cold press machines utilize centrifugal force for separation of oil from plant liquid.

Cold-press machine and working

As we know that it is a mechanical process of oil separation.

Traditionally, raw material was first grounded into a paste and this was pressed with a heavy stone mill turned by bullocks until it extracts the oil. But with the advent of technology, cold press machines are used.

Today, there are various cold press extraction methods are available which depends on the part of the plant oil that we have to extract. Bladder press extraction, Hydraulic presses, low resistance expeller pressing, modified atmosphere crushing and modified atmosphere packaging are some of latest extraction methods. Presses vary in their size; it is available in small size for home use and also has commercial or industrial use presses for oil extraction. Cold press machine has one inlet for feeding raw material or seed and two outlets or exits. One exit is for extracted oil and other is for non-oiled cake.

cold press working

Raw material for the process (seeds, nuts, or fruits) are collected and thoroughly cleaned to get rid of impurities. Take for instance our material is seeds. Seeds are then placed inside a cylinder that contains rotating screw.

When the machine is activated, screw helps in grinding and crushing of seeds, and exposes the oil containing sacs until the oil is extracted. Small holes in the bottom of the cylinder allow oil to escape in the collection container. It is then strained to avoid any solid pulp pieces and to maintain quality.

As the screw breaks the seeds, friction force causes generation of heat. But this heat is not enough to damage the oil. This is referred as first pressed oil which is generally sold unrefined and without any chemical additives or preservatives and this is actual cold pressed oil. The oil extracted from the first pressing is of finest quality and purity.

Benefits of cold pressed oils

There are multitude benefits of cold pressed technique and one should know about such 
     added benefits. This helps to make good choice when you shop for your favorite oil. I have
     listed below benefits of cold pressed oils:         

  • Cold pressed oil involves no external heat and so they are loaded with essential antioxidants and vitamins.
  • They are rich in Vitamin E.
  • Cold pressed oil has biological activities like antibacterial and anti-inflammatory that prevents exposure to infections.
  • Heat generally degrades Vitamin C. Thus cold pressed oil acts as good source of Vitamin C which penetrates into the skin and provides healthy skin.
  • Cold pressed oils are pure oils and are best oils in terms of purity. This is because the oil has been forced out by pressure and no application of heat or harmful chemicals has been added.
  • Cold pressed oils are generally employed for carrier oils. Some of these oils are rich source of oleic acid which boosts immunity.
  • Cold pressed oil also contains cancer fighting properties.
  • Carrier oils are generally odorless and some edible oils like olive oil retain good flavor because of cold press method. So these edible cold pressed oils are used for cooking and baking.
  • Cold pressed oils have various benefits for skin and hair.

What is CO2 extraction

Among several supercritical fluid (abbreviated SCF) technologies, the earliest developed, most researched and industrialized product technology is undoubtedly the supercritical fluid extraction (abbreviated SFE) technology.

Supercritical fluid extraction (SFE) is the process of separating one component (the extractant) from another (the matrix) using supercritical fluids as the extracting solvent.

Supercritical CO2 extraction (SCFE) is used particularly in the food, beverage, cosmetics and pharmaceutical industry for extracting natural substances, aromas, fats, oils, waxes, polymers, enzymes and colourants in their supercritical physical state.

CO2 is a natural and environmentally-friendly solvent which has advantages over synthetic and harmful media such as n-hexane when it comes to sustainability.

CO2 Extraction Process
The process of supercritical CO2 extraction of essential oils


Supercritical extraction uses a supercritical fluid as the separation medium (extractant), and uses the fluid to have a highly enhanced dissolving ability in a supercritical state to achieve effective extraction of certain components (solutes) in the raw material, and then pass the temperature and The continuous adjustment of the pressure can reduce the density of the extractant, that is, reduce its solubility to the solute, so as to achieve high-efficiency separation of specific components in the raw material.


Because supercritical fluid has excellent mass transfer characteristics of gas and solvation ability equivalent to liquid solvents, supercritical extraction using it as a separation medium is considered to integrate the two unit operations of distillation and liquid-liquid extraction to a certain extent.
The advantages of this form a unique separation technology. The basis of the theory is the phase equilibrium relationship of the fluid mixture in the supercritical state, which operates in the mass transfer process.


CO2 extracted material is free of residual solvents.
Nothing is left behind once the extraction is over since the carbon dioxide bubbles away, leaving no trace in the end product.


Comparing CO2 cannabis extraction to butane or propane? Don’t forget to include the facility costs for processing with compressed flammable gas.
CO2 extraction is often used in the extraction of plant essential oils